These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Electrocatalytic nitrogen reduction to ammonia at low potential using a phenalenyl-based iron(III) complex.
    Author: Waghela SR, Adalder A, Bhattacharjee J, Mukherjee N, Paul S, Ghorai UK.
    Journal: Dalton Trans; 2024 Oct 08; 53(39):16154-16158. PubMed ID: 39320430.
    Abstract:
    In recent years, electrochemical nitrogen reduction reaction (ENRR) has emerged as a promising alternative for ammonia production in a clean and energy-efficient manner. We reported the remarkable performance of a transition metal-based electrocatalyst, Fe(III)(PLY)3 (where PLY-H = 9-hydroxyphenalenone), for electrochemical NRR. In an acidic electrolyte, Fe(PLY)3 catalyst demonstrates remarkable performance, achieving a high faradaic efficiency (FE) of 43.4% and an impressive ammonia (NH3) yield rate of 99.7 μg h-1 mgcat-1 at -0.2 V compared to a reversible hydrogen electrode (RHE).
    [Abstract] [Full Text] [Related] [New Search]