These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Formation of bijels stabilized by magnetic ellipsoidal particles in external magnetic fields.
    Author: Karthikeyan N, Schiller UD.
    Journal: Soft Matter; 2024 Nov 20; 20(45):8952-8967. PubMed ID: 39387401.
    Abstract:
    Bicontinuous interfacially-jammed emulsion gels (bijels) are increasingly used as emulsion templates for the fabrication of functional porous materials including membranes, electrodes, and biomaterials. Control over the domain size and structure is highly desirable in these applications. For bijels stabilized by spherical particles, particle size and volume fraction are the main parameters that determine the emulsion structure. Here, we investigate the use of ellipsoidal magnetic particles and study the effect of external magnetic fields on the formation of bijels. Using hybrid Lattice Boltzmann-molecular dynamics simulations, we analyze the effect of the magnetic field on emulsion dynamics and the structural properties of the resulting bijel. We find that the formation of bijels remains robust in the presence of magnetic fields, and that the domain size and tortuosity become anisotropic when ellipsoidal particles are used. We show that the magnetic fields lead to orientational ordering of the particles which in turn leads to alignment of the interfaces. The orientational order facilitates enhanced packing of particles in the interface which leads to different jamming times in the directions parallel and perpendicular to the field. Our results highlight the potential of magnetic particles for fabrication and processing of emulsion systems with tunable properties.
    [Abstract] [Full Text] [Related] [New Search]