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  • Title: Photocatalytic Enhancement and Recyclability in Visible-Light-Responsive 2D/2D g-C3N4/BiOI p-n Heterojunctions via a Z-Scheme Charge Transfer Mechanism.
    Author: Yang S, Wu T, Li K, Huang P, Li W, Zhuo Y, Liu K, Yang Z, Han D.
    Journal: Molecules; 2024 Nov 17; 29(22):. PubMed ID: 39598807.
    Abstract:
    With the intensification of the energy crisis and the growing concern over environmental pollution, particularly the discharge of organic dye pollutants in industrial wastewater, photocatalytic degradation of these contaminants using solar energy has emerged as an effective, eco-friendly solution. In this study, we successfully synthesized 2D/2D g-C3N4/BiOI p-n heterojunctions via a simple precipitation method and a high-temperature calcination method. The unique 2D structures of g-C3N4 nanosheets (NSs) and BiOI NSs, coupled with the synergistic effect between the two materials, significantly enhanced the photocatalytic degradation performance of the heterojunctions under simulated sunlight. The band structures, as determined by Tauc curves, Mott-Schottky curves and XPS-VB analysis, revealed a Z-scheme charge transfer mechanism that efficiently reduced charge carrier recombination and improved electron-hole separation. The photocatalytic activity of 2D/2D g-C3N4/BiOI p-n heterojunctions for rhodamine B (Rh B) degradation reached 99.7% efficiency within 60 min, a 2.37-fold and 1.27-fold improvement over pristine BiOI NSs and g-C3N4 NSs, respectively. Furthermore, the heterojunction exhibited excellent recyclability stability, with the degradation efficiency decreasing by only 1.2% after five cycles. Radical scavenging experiments confirmed the involvement of superoxide radicals (∙O2-) and hydroxyl radicals (∙OH) as the primary reactive species in the degradation process. This work highlights the potential of 2D/2D g-C3N4/BiOI p-n heterojunctions for efficient photocatalytic applications in environmental remediation.
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