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Title: Improved recovery and stability of ethanol in automated headspace analysis. Author: Christmore DS, Kelly RC, Doshier LA. Journal: J Forensic Sci; 1984 Oct; 29(4):1038-44. PubMed ID: 6502105. Abstract: Solutions are reported here for two problems in automated headspace gas chromatographic analysis for ethanol. The first is the catalytic oxidation of ethanol by oxyhemoglobin, a process that is limited only by the amount of oxygen in the sealed vessel. This reaction is prevented by the addition of sodium dithionite. The other problem, the lack of a suitable salting-out agent, led to the selection of ammonium sulfate, which improved recovery of ethanol as well as enhancing method precision. A procedure incorporating these improvements is described.[Abstract] [Full Text] [Related] [New Search]