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  • Title: Syntheses of 6'-C-aminomethyl-3'-deoxyparomamines.
    Author: Yamaguchi T, Tsuchiya T, Umezawa S.
    Journal: J Antibiot (Tokyo); 1977 Jan; 30(1):71-5. PubMed ID: 838633.
    Abstract:
    The first synthesis of 6'-C-aminomethyl derivatives (6'-epimers) of 3'-deoxyparomamine is reported starting from 3'-deoxyparomamine by way of 6'-O-tritylation, O-acetylation, hydrolysis of the trityl group, conversion of the 6'-hydroxyl group into an aldehyde group, nitromethane condensation of the aldehyde group and catalytic reduction of the nitro group into an amino group.
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