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  • Title: Gas chromatographic determination of Ostwald solubility coefficients for cyclopropane, halothane and trichloroethene (trichloroethylene).
    Author: Halliday MM, MacDonald I, MacGregor MH.
    Journal: Br J Anaesth; 1977 May; 49(5):413-7. PubMed ID: 861107.
    Abstract:
    Gas chromatographic methods using solvent extraction for the analysis of cyclopropane and and trichloroethene (trichloroethylene) are described and evaluated; cyclopropane was extracted into carbon tetrachloride and trichloroethene into carbon disulphide, using chloroform and toluene respectively as the internal standards. Ostwald solubility coefficients were measured for cyclopropane, halothane and trichloroethene in Krebs solution: at 310 K the respective values +/- SEM of the Ostwald coefficients are 0.181 +/- 0.009, 0.78 +/- 0.02 and 1.54 +/- 0.02; over the temperature range 295-310 K the respective temperature coefficients of solubility are -2.27, -4.18 and -3.81 in units of per cent/K at 310 K.
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