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327 related items for PubMed ID: 12553844

  • 1. Normal and inverse primary kinetic deuterium isotope effects for C-H bond reductive elimination and oxidative addition reactions of molybdenocene and tungstenocene complexes: evidence for benzene sigma-complex intermediates.
    Churchill DG, Janak KE, Wittenberg JS, Parkin G.
    J Am Chem Soc; 2003 Feb 05; 125(5):1403-20. PubMed ID: 12553844
    [Abstract] [Full Text] [Related]

  • 2. Zwitterionic and cationic bis(phosphine) platinum(II) complexes: structural, electronic, and mechanistic comparisons relevant to ligand exchange and benzene C-H activation processes.
    Thomas JC, Peters JC.
    J Am Chem Soc; 2003 Jul 23; 125(29):8870-88. PubMed ID: 12862484
    [Abstract] [Full Text] [Related]

  • 3. Reductive elimination/oxidative addition of carbon-hydrogen bonds at Pt(IV)/Pt(II) centers: mechanistic studies of the solution thermolyses of Tp(Me2)Pt(CH3)2H.
    Jensen MP, Wick DD, Reinartz S, White PS, Templeton JL, Goldberg KI.
    J Am Chem Soc; 2003 Jul 16; 125(28):8614-24. PubMed ID: 12848569
    [Abstract] [Full Text] [Related]

  • 4. Structure and reactivity of bis(silyl) dihydride complexes (PMe(3))(3)Ru(SiR(3))(2)(H)(2): model compounds and real intermediates in a dehydrogenative C-Si bond forming reaction.
    Dioumaev VK, Yoo BR, Procopio LJ, Carroll PJ, Berry DH.
    J Am Chem Soc; 2003 Jul 23; 125(29):8936-48. PubMed ID: 12862491
    [Abstract] [Full Text] [Related]

  • 5. Insertion reactions of alkynes and organic isocyanides into the palladium-carbon bond of dimetallic Fe-Pd alkoxysilyl complexes.
    Knorr M, Jourdain I, Braunstein P, Strohmann C, Tiripicchio A, Ugozzoli F.
    Dalton Trans; 2006 Nov 28; (44):5248-58. PubMed ID: 17088964
    [Abstract] [Full Text] [Related]

  • 6. Temperature-dependent transitions between normal and inverse isotope effects pertaining to the interaction of H-H and C-H bonds with transition metal centers.
    Parkin G.
    Acc Chem Res; 2009 Feb 17; 42(2):315-25. PubMed ID: 19133745
    [Abstract] [Full Text] [Related]

  • 7. A two-state computational investigation of methane C--H and ethane C--C oxidative addition to [CpM(PH3)]n+ (M = Co, Rh, Ir; n = 0, 1).
    Petit A, Richard P, Cacelli I, Poli R.
    Chemistry; 2006 Jan 11; 12(3):813-23. PubMed ID: 16331716
    [Abstract] [Full Text] [Related]

  • 8. Silylene hydride complexes of molybdenum with silicon-hydrogen interactions: neutron structure of (eta(5)-C(5)Me(5))(Me(2)PCH(2)CH(2)PMe(2))Mo(H)(SiEt(2)).
    Mork BV, Tilley TD, Schultz AJ, Cowan JA.
    J Am Chem Soc; 2004 Aug 25; 126(33):10428-40. PubMed ID: 15315459
    [Abstract] [Full Text] [Related]

  • 9. Molybdenocene trihydride complexes: influence of a [Me2Si] ansa bridge on classical versus nonclassical nature, stability with respect to elimination of dihydrogen, and acidity.
    Janak KE, Shin JH, Parkin G.
    J Am Chem Soc; 2004 Oct 13; 126(40):13054-70. PubMed ID: 15469304
    [Abstract] [Full Text] [Related]

  • 10. Synthesis and reactivity of silyl ruthenium complexes: the importance of trans effects in C-H activation, Si-C bond formation, and dehydrogenative coupling of silanes.
    Dioumaev VK, Procopio LJ, Carroll PJ, Berry DH.
    J Am Chem Soc; 2003 Jul 02; 125(26):8043-58. PubMed ID: 12823028
    [Abstract] [Full Text] [Related]

  • 11. Combined experimental and computational studies on carbon-carbon reductive elimination from Bis(hydrocarbyl) complexes of (PCP)Ir.
    Ghosh R, Emge TJ, Krogh-Jespersen K, Goldman AS.
    J Am Chem Soc; 2008 Aug 27; 130(34):11317-27. PubMed ID: 18680287
    [Abstract] [Full Text] [Related]

  • 12. The synthesis, characterisation and reactivity of 2-phosphanylethylcyclopentadienyl complexes of cobalt, rhodium and iridium.
    McConnell AC, Pogorzelec PJ, Slawin AM, Williams GL, Elliott PI, Haynes A, Marr AC, Cole-Hamilton DJ.
    Dalton Trans; 2006 Jan 07; (1):91-107. PubMed ID: 16357965
    [Abstract] [Full Text] [Related]

  • 13. Dicarbollylamine ligand as a tunable template for sigma,sigma- and pi,sigma-bonding modes: syntheses, structures, and theoretical studies of eta5:eta1-coordinated constrained-geometry group 13 metal complexes.
    Lee JD, Kim SK, Kim TJ, Han WS, Lee YJ, Yoo DH, Cheong M, Ko J, Kang SO.
    J Am Chem Soc; 2008 Jul 30; 130(30):9904-17. PubMed ID: 18597462
    [Abstract] [Full Text] [Related]

  • 14. Computational evidence that the inverse kinetic isotope effect for reductive elimination of methane from a tungstenocene methyl-hydride complex is associated with the inverse equilibrium isotope effect for formation of a sigma-complex intermediate.
    Janak KE, Churchill DG, Parkin G.
    Chem Commun (Camb); 2003 Jan 07; (1):22-3. PubMed ID: 12610946
    [Abstract] [Full Text] [Related]

  • 15. Intermolecular C-H bond activation reactions promoted by transient titanium alkylidynes. Synthesis, reactivity, kinetic, and theoretical studies of the Ti[triple bond]C linkage.
    Bailey BC, Fan H, Huffman JC, Baik MH, Mindiola DJ.
    J Am Chem Soc; 2007 Jul 18; 129(28):8781-93. PubMed ID: 17592842
    [Abstract] [Full Text] [Related]

  • 16. Intermolecular activation of hydrocarbon C-H bonds under ambient conditions by 16-electron neopentylidene and benzyne complexes of molybdenum.
    Wada K, Pamplin CB, Legzdins P, Patrick BO, Tsyba I, Bau R.
    J Am Chem Soc; 2003 Jun 11; 125(23):7035-48. PubMed ID: 12783558
    [Abstract] [Full Text] [Related]

  • 17. Adding a new dimension to the investigation of platinum-mediated arene C-H activation reactions using 2D NMR exchange spectroscopy. Dynamics of Pt(II) phenyl/benzene site exchange.
    Wik BJ, Lersch M, Krivokapic A, Tilset M.
    J Am Chem Soc; 2006 Mar 01; 128(8):2682-96. PubMed ID: 16492055
    [Abstract] [Full Text] [Related]

  • 18. On the mechanisms of degenerate ligand exchange in [M(CH(3))](+)/CH(4) Couples (M=Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt) as explored by mass spectrometric and computational studies: oxidative addition/reductive elimination versus sigma-complex-assisted metathesis.
    Armélin M, Schlangen M, Schwarz H.
    Chemistry; 2008 Mar 01; 14(17):5229-36. PubMed ID: 18435447
    [Abstract] [Full Text] [Related]

  • 19. Cationic hafnium silyl complexes and their enhanced reactivity in sigma-bond metathesis processes with Si-H and C-H bonds.
    Sadow AD, Tilley TD.
    J Am Chem Soc; 2003 Aug 06; 125(31):9462-75. PubMed ID: 12889977
    [Abstract] [Full Text] [Related]

  • 20. Evidence for the involvement of 5f orbitals in the bonding and reactivity of organometallic actinide compounds: thorium(IV) and uranium(IV) bis(hydrazonato) complexes.
    Cantat T, Graves CR, Jantunen KC, Burns CJ, Scott BL, Schelter EJ, Morris DE, Hay PJ, Kiplinger JL.
    J Am Chem Soc; 2008 Dec 24; 130(51):17537-51. PubMed ID: 19053455
    [Abstract] [Full Text] [Related]

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