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2. Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu3P)2. Shi JC, Zeng X, Negishi E. Org Lett; 2003 May 29; 5(11):1825-8. PubMed ID: 12762662 [Abstract] [Full Text] [Related]