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160 related items for PubMed ID: 19998305

  • 1. Gas-phase kinetics of chlorosilylene reactions II. ClSiH + C2H4: absolute rate measurements and quantum chemical and RRKM calculations for the prototype pi addition reaction.
    Becerra R, Boganov SE, Egorov MP, Krylova IV, Nefedov OM, Promyslov VM, Walsh R.
    Chemphyschem; 2010 Feb 01; 11(2):419-28. PubMed ID: 19998305
    [Abstract] [Full Text] [Related]

  • 2. Gas-phase kinetics of chlorosilylene reactions. I. ClSiH + Me3SiH: absolute rate measurements and theoretical calculations for prototype Si-H insertion reactions.
    Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Promyslov VM, Walsh R.
    J Phys Chem A; 2009 May 14; 113(19):5512-8. PubMed ID: 19382797
    [Abstract] [Full Text] [Related]

  • 3. The addition reaction between silylene and ethyne: further isotope studies, pressure dependence studies, and quantum chemical calculations.
    Becerra R, Cannady JP, Dormer G, Walsh R.
    J Phys Chem A; 2008 Sep 18; 112(37):8665-77. PubMed ID: 18714973
    [Abstract] [Full Text] [Related]

  • 4. The gas-phase reaction between silylene and 2-butyne: kinetics, isotope studies, pressure dependence studies and quantum chemical calculations.
    Becerra R, Cannady JP, Dormer G, Walsh R.
    Phys Chem Chem Phys; 2009 Jul 14; 11(26):5331-44. PubMed ID: 19551200
    [Abstract] [Full Text] [Related]

  • 5. Time-resolved gas-phase kinetic, quantum chemical and RRKM studies of reactions of silylene with cyclic ethers.
    Becerra R, Cannady JP, Goulder O, Walsh R.
    J Phys Chem A; 2010 Jan 21; 114(2):784-93. PubMed ID: 20028001
    [Abstract] [Full Text] [Related]

  • 6. Time-resolved gas-phase kinetic study of the germylene addition reaction, GeH2+CH3C[triple bond, length as m-dash]CCH3.
    Becerra R, Walsh R.
    Phys Chem Chem Phys; 2009 May 14; 11(18):3539-46. PubMed ID: 19421559
    [Abstract] [Full Text] [Related]

  • 7. Unusual isotope effect in the reaction of chlorosilylene with trimethylsilane-1-d. Absolute rate studies and quantum chemical and Rice-Ramsperger-Kassel-Marcus calculations provide strong evidence for the involvement of an intermediate complex.
    Becerra R, Boganov SE, Egorov MP, Krylova IV, Promyslov VM, Walsh R.
    J Am Chem Soc; 2012 Jun 27; 134(25):10493-501. PubMed ID: 22632068
    [Abstract] [Full Text] [Related]

  • 8. Time-resolved gas-phase kinetic and quantum chemical studies of the reaction of silylene with oxygen.
    Becerra R, Bowes SJ, Ogden JS, Cannady JP, Adamovic I, Gordon MS, Almond MJ, Walsh R.
    Phys Chem Chem Phys; 2005 Aug 07; 7(15):2900-8. PubMed ID: 16189609
    [Abstract] [Full Text] [Related]

  • 9. Time-resolved gas-phase kinetic, quantum chemical, and RRKM studies of reactions of silylene with alcohols.
    Becerra R, Cannady JP, Walsh R.
    J Phys Chem A; 2011 May 05; 115(17):4231-40. PubMed ID: 21469721
    [Abstract] [Full Text] [Related]

  • 10. Time-resolved gas-phase kinetic study of the germylene addition reaction, GeH(2) + C(2)D(2).
    Becerra R, Walsh R.
    Phys Chem Chem Phys; 2010 Mar 28; 12(12):2923-8. PubMed ID: 20449382
    [Abstract] [Full Text] [Related]

  • 11. Time-resolved gas-phase kinetic and quantum chemical studies of the reaction of silylene with nitric oxide.
    Becerra R, Bowes SJ, Ogden JS, Cannady JP, Almond MJ, Walsh R.
    J Phys Chem A; 2005 Feb 17; 109(6):1071-80. PubMed ID: 16833416
    [Abstract] [Full Text] [Related]

  • 12. Time-resolved gas-phase kinetic and quantum chemical studies of reactions of silylene with chlorine-containing species. 2. CH3Cl.
    Becerra R, Cannady JP, Walsh R.
    J Phys Chem A; 2006 Jun 01; 110(21):6680-6. PubMed ID: 16722683
    [Abstract] [Full Text] [Related]

  • 13. Gas phase kinetic and quantum chemical studies of the reactions of silylene with the methylsilanes. Absolute rate constants, temperature dependences, RRKM modelling and potential energy surfaces.
    Becerra R, Carpenter IW, Gordon MS, Roskop L, Walsh R.
    Phys Chem Chem Phys; 2007 May 07; 9(17):2121-9. PubMed ID: 17464393
    [Abstract] [Full Text] [Related]

  • 14. A comparison of the reactivity of germylene and dimethylgermylene with some methylgermanes. Direct kinetic and quantum chemical studies.
    Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Promyslov VM, Walsh R.
    Phys Chem Chem Phys; 2007 Aug 21; 9(31):4395-406. PubMed ID: 17687486
    [Abstract] [Full Text] [Related]

  • 15. Direct time-resolved study of the gas-phase reactions of germylene with ethyl- and diethylgermane: absolute rate constants, temperature dependences, and mechanism.
    Becerra R, Boganov SE, Egorov MP, Krylova IV, Nefedov OM, Walsh R.
    J Phys Chem A; 2007 Mar 01; 111(8):1434-40. PubMed ID: 17279735
    [Abstract] [Full Text] [Related]

  • 16. Time-Resolved Gas-Phase Kinetic, Quantum Chemical, and RRKM Studies of the Reaction of Silylene with 2,5-Dihydrofuran.
    Becerra R, Cannady JP, Pfrang C, Walsh R.
    J Phys Chem A; 2015 Nov 19; 119(46):11241-53. PubMed ID: 26487151
    [Abstract] [Full Text] [Related]

  • 17. Time-resolved gas-phase kinetic studies of the reaction of dimethylsilylene with triethylsilane-1-d: kinetic isotope effect for the Si-H insertion process.
    Becerra R, Cannady JP, Walsh R.
    Phys Chem Chem Phys; 2013 Apr 21; 15(15):5530-8. PubMed ID: 23455034
    [Abstract] [Full Text] [Related]

  • 18. Surprisingly slow reaction of dimethylsilylene with dimethylgermane: time-resolved kinetic studies and related quantum chemical calculations.
    Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Promyslov VM, Walsh R.
    J Phys Chem A; 2008 Feb 07; 112(5):849-57. PubMed ID: 18193853
    [Abstract] [Full Text] [Related]

  • 19. Pulsed laser photolysis and quantum chemical-statistical rate study of the reaction of the ethynyl radical with water vapor.
    Carl SA, Nguyen HM, Elsamra RM, Nguyen MT, Peeters J.
    J Chem Phys; 2005 Mar 15; 122(11):114307. PubMed ID: 15836215
    [Abstract] [Full Text] [Related]

  • 20. Experimental and theoretical evidence for homogeneous catalysis in the gas-phase reaction of SiH(2) with H(2)O (and D(2)O): a combined kinetic and quantum chemical study.
    Becerra R, Goldberg N, Cannady JP, Almond MJ, Ogden JS, Walsh R.
    J Am Chem Soc; 2004 Jun 02; 126(21):6816-24. PubMed ID: 15161310
    [Abstract] [Full Text] [Related]

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